Search results for " hydrogen storage"

Density functional theory based screening of ternary alkali-transition metal borohydrides: a computational material design project.

2009

We present a computational screening study of ternary metal borohydrides for reversible hydrogen storage based on density functional theory. We investigate the stability and decomposition of alloys containing 1 alkali metal atom, Li, Na, or K M1; and 1 alkali, alkaline earth or 3d / 4d transition metal atom M2 plus two to five BH4  groups, i.e., M1M2BH42‐5, using a number of model structures with trigonal, tetrahedral, octahedral, and free coordination of the metal borohydride complexes. Of the over 700 investigated structures, about 20 were predicted to form potentially stable alloys with promising decomposition energies. The M1Al/ Mn/ FeBH44, Li/ NaZnBH43, and Na/ KNi/ CoBH43 alloys are …

Smart multi-carrier energy system: Optimised energy management and investment analysis

2016

This paper proposes an optimised Energy Management System for a multi-carrier hub, which integrates two energy distribution networks, for hydrogen and electricity. The economic sustainability of a real-life instantiation of such a system has been analysed as well. The Energy Management System has been developed by means of a multi-objective optimisation algorithm, the Non-dominated Sorting Genetic Algorithm II, implemented using MATLAB®. The achieved results consist in a series of set-points defining the working conditions of the plant for a chosen time horizon. Data provided by this process also show the effectiveness of the adopted optimisation approach. The financial analysis is performe…

Synthesis and characterization of nanocrystalline LaNi5 hydrogen storage materials

2009

With the growing environmental concerns of greenhouse gas emissions from the burning of fossil fuels, it is becoming increasingly important to switch to cleaner alternative fuels such as hydrogen [1]. Inter-metallic LaNi5 is one of the most widely used and studied solid-state hydrogen storage material – a pet material for the prototype systems using hydrogen fuel. However, nanostructuring effects on this systems are not yet fully explored. Recently we have carried out systematic studies regarding the effect of nanostructuring on the hydrogen sorption properties of this material [2]. Unlike some other potential hydrogen storage materials, which shows faster kinetics upon nanostructuring, the…

Novel conception materials based on polymeric Matrix for H2 storage

2012